The Peterson olefination using the tert-butyldiphenylsilyl group: Stereoselective synthesis of di- and trisubstituted alkenes

Authors
Barbero, A Blanco, Y Garcia, C Pulido, FJ
Citation
A. Barbero et al., The Peterson olefination using the tert-butyldiphenylsilyl group: Stereoselective synthesis of di- and trisubstituted alkenes, SYNTHESIS-S, (9), 2000, pp. 1223-1228
Citations number
42
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
9
Year of publication
2000
Pages
1223 - 1228
Database
ISI
SICI code
0039-7881(200008):9<1223:TPOUTT>2.0.ZU;2-L
Abstract
The reaction of alpha-tert-butyldiphenylsilyl carbonyl compounds with organ ometallics leads with a high diastereoselectivity to erythro-beta-hydroxysi lanes, which under acidic or basic elimination conditions give E or Z di- a nti trisubstituted alkenes.