C. Aubauer et al., Synthesis, crystal structure, and vibrational spectra of dimethylphosphonium tetrachloroaluminate, H2PMe2+AlCl4-, Z ANORG A C, 626(8), 2000, pp. 1783-1786
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
H2PMe2+AlCl4- was synthesized by the reaction of Me2PH with HCl and AlCl3 i
n CH2Cl2. The structure of the compound was determined by X-ray structure d
etermination. H2PMe2+AlCl4- crystallizes in the monoclinic space group P2(1
)/c with a = 14.445(1), b = 11.344(1) and c = 12.394(1) Angstrom, beta = 90
.00(1)degrees, with 8 formula units per unit cell. The frequencies obtained
by Raman and infrared spectroscopy were assigned to the normal modes of th
e H2PMe2+ and AlCl4- units.