Organotin(IV) chloride complexes with phosphocholine and dimyristoyl-L-alpha-phosphatidylcholine

Authors
Grigoriev, EV Pellerito, L Yashina, NS Pellerito, C Petrosyan, VS
Citation
Ev. Grigoriev et al., Organotin(IV) chloride complexes with phosphocholine and dimyristoyl-L-alpha-phosphatidylcholine, APPL ORGAN, 14(8), 2000, pp. 443-448
Citations number
19
Categorie Soggetti
Chemistry
Journal title
APPLIED ORGANOMETALLIC CHEMISTRY
ISSN journal
02682605 → ACNP
Volume
14
Issue
8
Year of publication
2000
Pages
443 - 448
Database
ISI
SICI code
0268-2605(200008)14:8<443:OCCWPA>2.0.ZU;2-P
Abstract
Several complexes of RnSnCl4-n (R = Me, Ph, n = 1-3; R = nBu, n = 2, 3) wit h phosphocholine and dimyristoyl-L-alpha-phosphatidylcholine (phospholipid) have been synthesized and characterized by means of Mossbauer spectroscopy and NMR, Triorganotin chlorides form complexes of (R3SnCl)(2). L stoichiom etry with a trigonal bipyramidal pentacoordinate tin environment, while the others form 1:1 complexes with an octahedral hexacoordinate tin environmen t, with the ligands coordinating through anionic phosphodiester moieties in all cases. Copyright (C) 2000 John Wiley & Sons, Ltd.