We present a structural investigation of the polar (111) surface of CoO sin
gle crystals by grazing incidence X-ray diffraction. The surface is found t
o be always covered by a similar to 50 Angstrom-thick spinel Co3O4 layer th
at was quantitatively characterized. Attempts to remove this layer by UHV a
nnealings or Ar+ bombardments lead to the formation of metallic Co clusters
on the surface that transform again in Co3O4 by annealing under oxygen. (C
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