Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond

Authors
Gandelman, M Milstein, D
Citation
M. Gandelman et D. Milstein, Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond, CHEM COMMUN, (17), 2000, pp. 1603-1604
Citations number
41
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
17
Year of publication
2000
Pages
1603 - 1604
Database
ISI
SICI code
1359-7345(2000):17<1603:HCCAHO>2.0.ZU;2-J
Abstract
Reaction of [RhCl(COE)(2)](2) with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butylphosphinomethyl)-2,4,6-trimethylben zene (2) in dioxane under mild H-2 pressure results in selective catalytic activation of an unstrained C-N single bond.