A novel acetated 54-member crown-shaped polyoxomolybdate with unprecedented structural features: Na-26[{Na(H2O)(2)}(6)({mu(3)-OH)(4)(Mo20Mo34O164)-Mo-V-O-VI(mu(2)-CH3COO)(4)}]center dot approximate to 120H(2)O

Authors
Yang, WB Lu, CH Lin, X Zhuang, HH
Citation
Wb. Yang et al., A novel acetated 54-member crown-shaped polyoxomolybdate with unprecedented structural features: Na-26[{Na(H2O)(2)}(6)({mu(3)-OH)(4)(Mo20Mo34O164)-Mo-V-O-VI(mu(2)-CH3COO)(4)}]center dot approximate to 120H(2)O, CHEM COMMUN, (17), 2000, pp. 1623-1624
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
17
Year of publication
2000
Pages
1623 - 1624
Database
ISI
SICI code
1359-7345(2000):17<1623:ANA5CP>2.0.ZU;2-6
Abstract
The EPR silent acetated 54-member crown-shaped polyoxomolybdate Na-26[{Na(H 2O)(2)}(6)({mu(3)-OH)(4)(Mo20Mo34VI)-Mo-V- O-164(mu(2)-CH3COO)(4)}].approxi mate to 120H(2)O (1), constructed from two different but related building b locks in a new mode, is synthesized in high yield by reducing an acidified aqueous solution of Na2MoO4. 2H(2)O and CH3COONa . 3H(2)O.