Ma. Newton et al., Room temperature formation of rhodium nanoparticles on TiO2[110] via metalorganic chemical-vapour deposition (MOCVD) of [Rh(CO)(2)Cl](2), CHEM COMMUN, (17), 2000, pp. 1677-1678
Room temperature adsorption of [Rh(CO)(2)Cl](2) on TiO2[110] is investigate
d using Scanning Tunnelling Microscopy (STM) which reveals the formation of
nanoparticles that coexist with the mono-disperse Rh(CO)(2)Cl species; the
spatial distribution of these particles indicates that nanoparticle format
ion occurs principally at step edges.