Oxidation of [(cyclic triamine)(1,5-cyclooctadiene)iridium](+) cations by hydrogen peroxide forms metallaoxetanes

Authors
Flood, TC Iimura, M Perotti, JM Rheingold, AL Concolino, TE
Citation
Tc. Flood et al., Oxidation of [(cyclic triamine)(1,5-cyclooctadiene)iridium](+) cations by hydrogen peroxide forms metallaoxetanes, CHEM COMMUN, (17), 2000, pp. 1681-1682
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
17
Year of publication
2000
Pages
1681 - 1682
Database
ISI
SICI code
1359-7345(2000):17<1681:OO[TCB>2.0.ZU;2-R
Abstract
Iridaoxetane 3 formed by oxidation of 1 with aqueous H2O2 is isolated and c haracterized, providing a rare example of formation of a metallaoxetane by direct oxidation of a metal-alkene complex.