Studies on electrocatalytic performance of titanium oxide electrode modified with Pt toward the oxidation of methanol

Citation
H. Yang et al., Studies on electrocatalytic performance of titanium oxide electrode modified with Pt toward the oxidation of methanol, CHEM J CH U, 21(8), 2000, pp. 1283-1287
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
21
Issue
8
Year of publication
2000
Pages
1283 - 1287
Database
ISI
SICI code
0251-0790(200008)21:8<1283:SOEPOT>2.0.ZU;2-A
Abstract
Electrocatalytic performance of the Pr-TiOx/Ti electrode prepared with elec trochemical reduction-oxidation method toward the oxidation of methanol has been studied, The experimental results showed that the Pt-TiOx/Ti electrod e has a high electrocatalytic activity and good stability for the electroca talytic oxidation of methanol, By means of electrochemical, XPS, STM and in -situ FTIR techniques, it was found that one reason for the electrode to ex hibit an excellent performance is attributed to the high dispersion between nanosized Pt and TiOx particles, The low adsorption ability of the interme diate derived from methanol, such as linearly adsorbed CO species on the el ectrode surface due to the interaction between Pt and TiOx, also results in the excellent performance.