The influence of the concentration of sorbitan monooleate, decylpyridinium
chloride, and sodium dodecyl sulfate solutions on the stability of hydrophi
lic suspensions of SiO2 and CaF2 was studied. In the range of low surfactan
t concentrations, the sizes of the dispersed phase particles were found to
increase with surfactant concentration. At the surfactant concentrations lo
wer than a critical micellization concentration, the contact time of partic
les with the dispersion medium critically affects the aggregation stability
. At surfactant concentrations equal to the CMC, particle size distribution
does not change compared to the initial system and is independent of the c
ontact time of the particles with a solution.