Laser-induced fluorescence (LIF) has been used to detect AlO and TiO in low
pressure hydrogen/oxygen flames with added metalorganic precursors. Such f
lames are used for synthesis of alumina and titania nanopowders. Knowledge
of the monoxide profiles in these flames is useful in developing chemical m
odels for the complex pyrolysis of metalorganics in flames. Challenges to d
etection of AlO and TiO include strong scattering background from the parti
cle-laden flame, as well as interferences from broadband fluorescence. We p
resent strategies that allow for sensitive detection of these species in th
e presence of such interferences, with minimum temperature correction requi
red.