Polymerizable tautomers - 13. Synthesis and polymerization of a novel unsaturated tautomer, p-isopropenyl benzoylacetone

Authors
Masuda, S Kitamura, Y Minagawa, K Tanaka, M
Citation
S. Masuda et al., Polymerizable tautomers - 13. Synthesis and polymerization of a novel unsaturated tautomer, p-isopropenyl benzoylacetone, DES MON POL, 3(1), 2000, pp. 25-34
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
DESIGNED MONOMERS AND POLYMERS
ISSN journal
1385772X → ACNP
Volume
3
Issue
1
Year of publication
2000
Pages
25 - 34
Database
ISI
SICI code
1385-772X(2000)3:1<25:PT-1SA>2.0.ZU;2-N
Abstract
p-Isopropenyl benzoylacetone (IPBA), a novel unsaturated tautomer, was synt hesized from p-dichlorobenzene as the starting material and the solvent eff ect on its tautomerism was studied. Regression analysis of the tautomeric c onstants revealed that the equilibria depend on the polarity and hydrogen-b ond donor acidity of the solvents. Preliminary experiments on the polymeriz ation of IPBA were also performed.