Synthesis and magnetic and structural characterization of the first homoleptic lanthanide beta-ketoiminate

Authors
Rees, WS Just, O Castro, SL Matthews, JS
Citation
Ws. Rees et al., Synthesis and magnetic and structural characterization of the first homoleptic lanthanide beta-ketoiminate, INORG CHEM, 39(17), 2000, pp. 3736
Citations number
34
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
17
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000821)39:17<3736:SAMASC>2.0.ZU;2-8
Abstract
Unusual thermal robustness is exhibited by a homoleptic ytterbium complex, which sublimes intact at temperatures in excess of 500 degrees C/760 Torr. Employment of a (N)-nPr substituted ketoiminate ligand provides notable met al encapsulation and ensures integrity. The octahedral coordination sphere of the metal arrangement. substantial air stability and vapor-phase center is observed as a meridinal (O-3,N-3) arrangement.