The first mixed-valence fluorotin alkoxides: New sol-gel precursors of fluorine-doped tin oxide materials

Authors
Boegeat, D Jousseaume, B Toupance, T Campet, G Fournes, L
Citation
D. Boegeat et al., The first mixed-valence fluorotin alkoxides: New sol-gel precursors of fluorine-doped tin oxide materials, INORG CHEM, 39(17), 2000, pp. 3924
Citations number
34
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
17
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000821)39:17<3924:TFMFAN>2.0.ZU;2-2
Abstract
New mixed-valence fluorotin alkoxides; (SnSnF2)-Sn-II-F-IV(OR)(4) 1 (R = te tt-butyl, tert-amyl) were synthesized and characterized by multinuclear NMR and Mossbauer spectroscopies. The two tin sites are bridged via three mu(2 )(OR) groups. Adducts 1 yielded nanocrystalline conductive F-doped SnO2 pow ders by the sol-gel process. [GRAPHICS]