A new structural class of lanthanide carbonates: Synthesis, properties, and X-ray structure of the one-dimensional ch sin complex [Co(NH3)(6)](6)[K-2(H2O)(10)]-[Nd-2(CO3)(8)](2)center dot 20H(2)O

Authors
Bond, DL Clark, DL Donohoe, RJ Gordon, JC Gordon, PL Keogh, DW Scott, BL Tait, CD Watkin, JG
Citation
Dl. Bond et al., A new structural class of lanthanide carbonates: Synthesis, properties, and X-ray structure of the one-dimensional ch sin complex [Co(NH3)(6)](6)[K-2(H2O)(10)]-[Nd-2(CO3)(8)](2)center dot 20H(2)O, INORG CHEM, 39(17), 2000, pp. 3934
Citations number
58
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
17
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000821)39:17<3934:ANSCOL>2.0.ZU;2-Q
Abstract
The neodymium tetracarbonate complex [Co(NH3)(6)](6)-[K-2(H2O)(10)][Nd-2(CO 3)(8)](2). 20H(2)O (1) has bt:en prepared and characterized. A single-cryst al X-ray diffraction study of 1 reveals a pseudo-one-dimensional infinite c hain of nine-coordinate neodymium metal centers, each complexed by three bi dentate carbonate ligands in a pseudoequatorial fashion, while a fourth bid entate carbonate group occupies an axial coordination site on each metal an d acts as a mu(2)-eta(2),eta(1) bridge between adjacent chain units.