Gn. Mikhailova et al., Ion migration in high-T-c superconductors and the nature of the conductingstate in d-wave superconductors, INORG MATER, 36(8), 2000, pp. 807-815
The available experimental data on the ion migration in superconductingY-12
3 and Bi-2223 films under the effect of high transport currents are summari
zed. Irrespective of structural perfection, electrostimulated diffusion of
heavy ions and oxygen gives rise to the formation of new, stable phases and
partial degradation of superconductivity. A model taking into account the
proximity of the superconducting, structural, and magnetic transitions in h
igh-T-c materials is used to explain ion migration as the response of the s
ystem of ions and coherent d electrons to the external electric field. The
d-wave symmetry superconducting state is shown to possess combined, rotatio
nal + translational invariance, rotational symmetry being due to the motion
of electrons in the curl field of the ions, playing the role of topologica
l defects.