The initial stage of GaAs oxidation by a near-room-temperature liquid phase
chemical-enhanced technique has been studied. Based on the experimental re
sults of X-ray photoelectron spectroscopy, a complete model illustrating th
e chemical composition of the grown oxide film has been established. To cla
rify the kinetics of oxide growth in a liquid solution in more detail, we h
ave also performed selective oxidation and surface profile measurements. Un
usual features of the oxide growth kinetics have been observed by investiga
ting the physical structure of oxide at the edge of mask in the selective o
xidation.