Polarization switching and dielectric relaxations have been investigated in
two novel ferroelectric liquid crystal mixtures. The samples of helical pi
tch similar to 12 mu m and 0.43 mu m respectively were sandwiched in planar
cells of 5 mu m thickness. P-S, tau(r) and gamma have been evaluated using
polarization reversal current technique. Dielectric relaxation modes have
been studied under different bias conditions. In volume stabilized cell con
figuration (p(0) much less than d) bulk domain mode appears due to the form
ation of modulated domain structures in bulk region while in surface stabil
ized cell configuration (p(0) much greater than d) surface stabilized domai
n mode was observed. New relaxation mode appeared at all bias fields in SmC
* phase due to the surface effects.