We have experimentally observed the optical modes of periodic two-dimension
ally ordered polystyrene spheres with a diameter of 5.15 mu m using the att
enuated total reflection method. The dispersion relation of such optical mo
des clearly shows that there are two types of propagating modes in the orde
red spheres. We point out that one of the two optical modes is related to t
he guided modes in optical fibers and the periodicity of the spheres plays
an important role in its excitation mechanism. The other mode propagates al
ong spherical surfaces.