Preparation of organophilic Pd-montmorillonite, an efficient catalyst in alkyne semihydrogenation

Palladium particles incorporated into organophilic montmorillonite (Pd-M) w ere prepared via a novel synthetic method, mediated by a cationic surfactan t stabilizer. The materials were characterized by UV-Vis, ICP-AES, and TEM. Two representative samples (Pd-M1 and Pd-M2), with metal contents of 0.1% and 0.46%, respectively, were investigated in detail. TEM measurements indi cated that the diameters of the Pd particles observed were in the range 1.5 -6 nm. It is suggested that most of the Pd particles are situated on the ex ternal surface of the clay lamellae. Both Pd-M samples exhibited marked cat alytic activities and stereoselectivities in the liquid-phase hydrogenation of 1-phenyl-1-butyne. For the production of the cis-alkene stereoisomer, P d-M2 proved to be less active but more stereoselective than Pd-M1. The ster eoselectivities obtained for Pd-M2 in n-hexane (86-88%) were nearly as high as those experienced for the Lindlar catalyst. (C) 2000 Academic Press.