2D hexagonal grids assembled into 3D nets via Ag center dot center dot center dot Ag interactions

Authors
Zhang, HX Chen, ZN Su, CY Ren, C Kang, BS
Citation
Hx. Zhang et al., 2D hexagonal grids assembled into 3D nets via Ag center dot center dot center dot Ag interactions, J CHEM CRYS, 29(12), 1999, pp. 1239-1243
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
29
Issue
12
Year of publication
1999
Pages
1239 - 1243
Database
ISI
SICI code
1074-1542(199912)29:12<1239:2HGAI3>2.0.ZU;2-1
Abstract
A three-dimensional coordination polymer [Ni(en)(2)Ag-3(CN)(5)](n) (en = 1, 2-diaminoethane) was synthesized and characterized by X-ray crystallography . It crystallizes in the triclinic space group <P(1)over bar>, a = 7.520(2) Angstrom, b = 8.194(2) Angstrom, c = 8.426(2) Angstrom, alpha = 65.35(3)de grees, beta = 69.57(3)degrees, gamma = 68.91(3)degrees, V = 428.0(2), Angst rom(3) Z = 1. The 2D hexagonal grids are constructed using cyanides as brid ges, and the Ag ... Ag interactions between layers lead to a three-dimensio nal network.