A. Eich et al., Electro- and magneto-rheology of nematic liquid crystals: Experiment and nonequilibrium molecular dynamics computer simulation, J CHEM PHYS, 113(9), 2000, pp. 3829-3838
The viscosity of the nematic liquid crystal PCH-5 [4-(trans-4'-pentylcycloh
exyl)-benzonitrile], measured in the presence of an electric field parallel
to the gradient of the velocity, shows a complex dependence both on magnit
ude E of the electric field and on the shear rate (gamma) over dot. When pl
otted versus E-2/(gamma) over dot, all data points fall unto a master curve
. In nonequilibrium molecular dynamics computer simulations, performed for
a Gay-Berne model fluid, the corresponding influence of a magnetic field on
the viscosity was calculated. In both cases, the shape of the master curve
for the viscosity can be computed by considering the competition between t
he torques exerted by the velocity gradient and by the orienting field. It
involves the Leslie viscosity coefficients gamma(1) and gamma(2), the Mieso
wicz and Helfrich viscosities eta(1),eta(2), and eta(12). Thus it should be
possible to extract these coefficients from the data. This is straightforw
ard in the magnetic case since the molecules in the fluid "see" the externa
lly applied field. The internal electric field, however, differs from the a
pplied field E. When this effect is taken into account, using the known exp
erimental values for dielectric coefficients epsilon(parallel to) and epsil
on(perpendicular to), the electro-rheological master curve agrees very well
with the experimental data. Values for the viscosity coefficients are obta
ined and presented. (C) 2000 American Institute of Physics. [S0021-9606(00)
71433-4].