Electrically induced dynamic processes in nematic liquid crystals: H-1 nuclear magnetic resonance investigations

Citation
M. Bender et al., Electrically induced dynamic processes in nematic liquid crystals: H-1 nuclear magnetic resonance investigations, J CHEM PHYS, 113(6), 2000, pp. 2430-2439
Citations number
28
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
113
Issue
6
Year of publication
2000
Pages
2430 - 2439
Database
ISI
SICI code
0021-9606(20000808)113:6<2430:EIDPIN>2.0.ZU;2-7
Abstract
The director reorientation of some nematic liquid crystals in the presence of both magnetic and electric field is described by a modified from of the Leslie equation. Proton nuclear magnetic resonance experiments observing st atic director orientations in different angles between the director and the magnetic field are described together with reorientation experiments drive n by various electric fields. A new technique to measure Delta chi/Delta ep silon is presented which gives direct access to the anisotropies without an y influence of elastic properties. Using electric fields of different stren gth and in different angles with respect to the magnetic field the dynamic processes in liquid crystals can be investigated in a very flexible way. A number of experiments investigating the homogeneous director reorientation in the electric field is presented. As one result the rotational viscosity was determined. As a surprising result we found a homogeneous reorientation in the electric field and an inhomogeneous reorientation back in the magne tic field even though the initial angles between the director and the exter nal field were the same. (C) 2000 American Institute of Physics. [S0021-960 6(00)71130-5].