V. Tsukanova et al., Second-harmonic probe of pressure-induced structure ordering within long-chain fluorescein monolayer at the air/water interface, J PHYS CH B, 104(32), 2000, pp. 7707-7712
Pressure-induced structure ordering of long-chain Fluorescein O322 molecule
s within the monolayer at the air/water interface was studied by rotating a
sample trough using the second-harmonic generation technique. Azimuthal an
gle dependences of the polarized second-harmonic intensity (I-pp, I-ps, I-s
s, and I-sp) were measured for different degrees of monolayer compression.
I-pp and I-ss showed a 2-fold pattern, whereas I-ps and I-sp showed a 4-fol
d pattern. A set of theoretical equations was derived to interpret the obse
rved pattern. The observed patterns agreed with the equations based on C-2v
symmetry, and the monolayer showed a definite crystalline structure in the
0.21 nm(2)/molecule region. These results showed that the transition of an
initially disordered and heterogeneous dye monolayer into a fairly regular
crystalline-like structure was characterized by continuous changes in the
structure ordering of constituent molecules maintaining C-2v symmetry.