Improvement of calcium modified lead titanate piezoceramics by hot isostatic pressing

The hot isostatic pressing (HIP) is used in this work as a post-sintering t reatment to obtain piezoelectric ceramics with very low contents of porosit y. The method is applied to calcium modified lead titanate ceramics with a wide range of microstructures, corresponding to successive sintering stages . The effects of HIP on the various cases are quantitatively determined, ch ecking the effectiveness of the treatment to reduce the porosity without fu rther grain growth. A combination of computer-aided image processing and me asurement with optical and scanning electron (SEM) micrographs and transmis sion electron microscopy (TEM) are used to characterise the microstructures . The effect of HIP on the porosity is different depending on the sintering stage of the ceramic. Their ferropiezoelectric behaviour is also evaluated in relation to the microstructural changes. (C) 2000 Elsevier Science Ltd. All rights reserved.