A mild and efficient method for the deoxygenation of alpha,beta-epoxyketones to enones

Authors
Rana, KK Roy, SC
Citation
Kk. Rana et Sc. Roy, A mild and efficient method for the deoxygenation of alpha,beta-epoxyketones to enones, J INDIAN CH, 76(11-12), 1999, pp. 545-546
Citations number
21
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF THE INDIAN CHEMICAL SOCIETY
ISSN journal
00194522 → ACNP
Volume
76
Issue
11-12
Year of publication
1999
Pages
545 - 546
Database
ISI
SICI code
0019-4522(199911/12)76:11-12<545:AMAEMF>2.0.ZU;2-E
Abstract
A mild and efficient method for the deoxygenation of alpha,beta-epoxyketone s to the corresponding enones in excellent yield has been developed using a titanium(III) radical initiator. The deoxygenation occurred with complete loss of stereochemistry in the products.