H. Abe et al., AMORPHIZATION IN ALUMINUM-OXIDE INDUCED BY ION IRRADIATION, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 127, 1997, pp. 170-175
Amorphization in sapphire induced by irradiation has been observed for
years but it is still in discussion whether displacements or implante
d ions have an important role for the amorphization. In this work, we
perform irradiation with high-energy heavy ions in thin film alpha-alu
mina below room temperature, so that the effects of atomic displacemen
ts, especially of damage cascades, can be revealed. Amorphization was
detected at temperatures from 90 K to 230 K under irradiation with 600
-900 keV xenon and krypton ions, while no amorphization was detected u
nder irradiation with argon nor oxygen ions. The critical energy densi
ty to induce amorphization is estimated. Four stages on the crystallin
e-to-amorphous transformation was observed from the temperature depend
ence of the dose-to-amorphization. The effect of damage cascades on th
e irradiation-induced amorphization and defect kinetics resulting in a
n increase of the dose-to-amorphization will be discussed.