K. Volz et al., ION-BEAM MODIFICATION OF SI SIC/SI LAYER SYSTEMS/, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 127, 1997, pp. 355-359
Buried, homogeneous silicon carbide (SiC) layers were formed in (100)
and (111) silicon by ion beam synthesis (IBS). In order to study the i
on beam induced epitaxial crystallization (IBIEC) of buried SiC layers
, the carbide layers were amorphized by irradiation with 2 MeV Si2+ io
ns at 300 K, followed by solid-phase epitaxial regrowth of surrounding
amorphized silicon layers. IBIEC experiments were performed at 320 de
grees and 600 degrees C using a 800 keV Si+ beam. It is shown by trans
mission electron microscopy and electron diffraction that IBIEC works
well on buried SiC layers and results in epitaxial recrystallization a
t considerably lower target temperatures than necessary for thermal an
nealing. The IBIEC process starts from both SiC/Si interfaces and may
be accompanied by heterogeneous nucleation of poly-SiC as well as inte
rfacial layer-by-layer amorphization, depending on irradiation conditi
ons. The structure of the recrystallized regions in dependence of dose
, dose rate, temperature and crystal orientation is described in detai
l.