The changes with oxidation time of the oxide outer surface roughness, the o
xide grain size and the oxidation rate constant k(c) for NiO growth on Ni w
ire studied at 800 degrees C in 1 atm oxygen. The roughness was determined
by optical interferometry establishing 2D-profiles and SD-images. Correlati
ons were found between the variations of the oxide outer surface roughness
or the k(c) values and the oxide grain size. These are attributed to the de
crease of the oxide grain boundary density with time, which induces a decre
ase of the effective diffusion coefficient. (C) 2000 Elsevier Science S.A.
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