Jn. Mitchell et al., ION IRRADIATION DAMAGE IN ILMENITE AT 100 K, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 127, 1997, pp. 629-633
A natural single crystal of ilmenite (FeTiO3) was irradiated at 100 K
with 200 keV Ar2+. Rutherford backscattering spectroscopy and ion chan
neling with 2 MeV He+ ions were used to monitor damage accumulation in
the surface region of the implanted crystal, At an irradiation fluenc
e of 1 x 10(15) Ar2+/cm(2), considerable near-surface He+ ion dechanne
ling was observed, to the extent that ion yield from a portion of the
aligned crystal spectrum reached the yield level of a random spectrum.
This observation suggests that the near-surface region of the crystal
was amorphized by the implantation. Cross-sectional transmission elec
tron microscopy and electron diffraction on this sample confirmed the
presence of a 150 nm thick amorphous layer. These results are compared
to similar investigations on geikielite (MgTiO3) and spinel (MgAl2O4)
to explore factors that may influence radiation damage response in ox
ides.