F. Brenscheidt et al., ANNEALING STUDIES OF CHROMIUM-IMPLANTED SILICON-NITRIDE CERAMICS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 127, 1997, pp. 677-680
The effect of chromium implantation and subsequent annealing on the ha
rdness and wear behaviour of a silicon nitride-based ceramic is invest
igated. Implantation energies were 200, 400, 1000 and 2000 keV, the fl
uence was 10(17) Cr2+ ions cm(-2) in all cases. The annealing temperat
ures were 800 degrees C, 1000 degrees C and 1200 degrees C. The phase
composition was determined with X-ray diffraction. Annealing at 800 de
grees C does not affect the crystal structure. At 1000 degrees C the a
lpha-Si3N4-phase is formed for 1 and 2 MeV implantation energy. At 120
0 degrees C, Cristobalite and Keiviite an formed at the lower implanta
tion energies; at higher energies alpha-Si3N4 is formed. We discuss th
e phase formation for the different implantation energies and annealin
g temperatures and the relationship with the observed hardness and wea
r.