Pw. Nebiker et al., MINIMIZING RADIATION-DAMAGE IN SILICON STRUCTURED WITH LOW-ENERGY FOCUSED ION-BEAMS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 127, 1997, pp. 897-900
Monocrystalline silicon has been irradiated with ion beams of differen
t energies (60 keV down to 100 eV) with fluences from 10(10)/cm(2) to
10(16)/cm(2). Ga, Si, Pr and Au ion beams have been used with a spot s
ize between 0.1 and 1 mu m Reflectivity at normal incidence at a wavel
ength of 785 nm and laser induced, modulated reflectivity have been ap
plied for the characterisation of the optical and surface properties o
f the samples after irradiation. Sputtering and deposition have been s
tudied by Atomic Force Microscopy (AFM). For keV energies an abrupt in
crease in reflectivity and modulated reflectivity has been found with
the onset of the amorphisation process at fluences around 10(14) to 10
(15) atoms/cm(2). Irradiation with silicon ions shows a smaller increa
se in reflectivity, since there is no enhanced optical absorption due
to implantation of metallic ions. Irradiation at energies below 1 keV
results in a three orders of magnitude lower defect production in comp
arison to higher energies. While AFM measurements of silicon irradiate
d with Au to fluences of 5 x 10(17)/cm(2) still showed removal of mate
rial down to an energy of 500 eV, irradiation with Si ions produced no
significant removal at any investigated energy. A minimum of crystal
damage per removed substrate atom has been found for sputtering with A
u and Ga at energies around 1 keV.