Kt. Kern et al., BORON AND NITROGEN IMPLANTATION OF STEELS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 127, 1997, pp. 972-976
Samples of four steels with varying chromium content were implanted wi
th boron and seperately with nitrogen. Implantation energy was 75 keV
in all cases. Implantation profiles were modeled using TRIM and determ
ined experimentally by ion beam analysis. Boron ion sources leading to
improved ion beams will be discussed, Material characterization inclu
ded tribology and nano-indentation, Implanted materials showed improve
ments in wear resistance in all cases involving boron implantation, wh
ile nitrogen implantation resulted in improved wear resistance for thr
ee of the four materials. Reduced coefficients of friction were observ
ed for boron implanted materials with a surface layer of amorphous car
bon. The improvement of wear rate due to implantation and reduced coef
ficient of friction due to the carbon layer were independent results a
llowing for separate control of these properties. Nano-indentation res
ults show an increase in the hardness of the implanted regions for two
of the materials, 1018 and 304. Results of micro-structural analysis
through grazing incidenceglancing angle X-ray diffraction showed iron-
nitride formation and in one case chromium-nitride formation, Evidence
of iron-boride compound formation in boron implanted materials has be
en seen.