Use of optically active cyclic N,N-dialkyl aminals in asymmetric induction

Authors
Citation
Me. Jung et A. Huang, Use of optically active cyclic N,N-dialkyl aminals in asymmetric induction, ORG LETT, 2(17), 2000, pp. 2659-2661
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
17
Year of publication
2000
Pages
2659 - 2661
Database
ISI
SICI code
1523-7060(20000824)2:17<2659:UOOACN>2.0.ZU;2-A
Abstract
[GRAPHICS] Cyclization of the optically active ketone N,N-dialkyl aminals A affords th e diastereomer B as the major product with diastereoselectivities ranging f rom nearly 1:1 to essentially 100:0 depending on the cyclization studied.