Aluminum- and boron-mediated C-glycoside synthesis from 1,2-anhydroglycosides

Authors
Rainier, JD Cox, JM
Citation
Jd. Rainier et Jm. Cox, Aluminum- and boron-mediated C-glycoside synthesis from 1,2-anhydroglycosides, ORG LETT, 2(17), 2000, pp. 2707-2709
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
17
Year of publication
2000
Pages
2707 - 2709
Database
ISI
SICI code
1523-7060(20000824)2:17<2707:AABCSF>2.0.ZU;2-T
Abstract
[GRAPHICS] This letter describes a single flask strategy to the synthesis of a alpha-C -glycosides from glycals. This protocol couples a glycal epoxidation reacti on with a C-2 alkoxy-directed carbon-carbon bond forming reaction.