Two trigonal Ni(silylene)(3) complexes

Citation
Ta. Schmedake et al., Two trigonal Ni(silylene)(3) complexes, ORGANOMETAL, 19(17), 2000, pp. 3263-3265
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
17
Year of publication
2000
Pages
3263 - 3265
Database
ISI
SICI code
0276-7333(20000821)19:17<3263:TTNC>2.0.ZU;2-K
Abstract
Two homoleptic Ni(silylene)(3) complexes, 1a and 2a, have been synthesized and characterized by X-ray crystallography. Due to steric constraints only three silylenes coordinate to the nickel, generating novel complexes that a re trigonal planar at the nickel center.