Studies on organophosphorus compounds V. reaction of 2,4-bis (4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide with cyclic and heterocyclicketones

Authors
Citation
Nr. Mohamed, Studies on organophosphorus compounds V. reaction of 2,4-bis (4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide with cyclic and heterocyclicketones, PHOSPHOR SU, 161, 2000, pp. 123-134
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
161
Year of publication
2000
Pages
123 - 134
Database
ISI
SICI code
1042-6507(2000)161:<123:SOOCVR>2.0.ZU;2-M
Abstract
Cyclic ketones 2 and 8a,b reacted with Lawesson's reagent (1) in different molar ratios to give the oxathiaphosphole (4), the disulfide 7 and the dith iones 9a,b. N-Methyl barbituric acid (10b) reacted with LR to produce the e nethiole 11 and the sulfide 12. Pyrazolone derivatives 13 and 17 reacted wi th LR in different molar ratios to form the corresponding products 15, 16 a nd 19. Rohdanine (20) reacted with LR to give the enethiole 22 and the disu lfide 23.