At atmospheric pressure, the electrical breakdown of a silent discharge can
occur in many thin filaments (leading to micro-discharges) or in a single
discharge canal covering the entire electrode surface (leading to a glow di
scharge). The aim of this paper is to contribute to a better understanding
of the transition from a glow silent discharge to micro-discharges in nitro
gen at atmospheric pressure. For this purpose, the two types of regime have
been studied by emission spectroscopy and electrical measurements. The tra
nsition is always observed due to an increase of the power dissipated in th
e gas gap, but the maximum power that can be used while maintaining a glow
discharge depends on the nature of the dielectric surface in contact with t
he gas. These results have been explained by the predominance of the densit
y of metastable nitrogen molecules on the discharge regime. Due to the crea
tion of seed electrons via Penning ionization, these metastable molecules c
an control the gas breakdown and so the discharge regime. Their density ess
entially depends on their quenching rate. The products etched from the surf
aces in contact with the discharge appear to be the main source of the meta
stable molecules quenching. Therefore, the nature of the surface controls t
he nature of the quenching of the metastable molecules and the power dissip
ated in the discharge the quencher density.