Organometallic tin(IV) derivatives of the ambidentate O-cholesteryl-O-phenyl phosphorothioate ligand

Authors
Lopez-Cardoso, M Garcia, PGY Rogers-Sakuma, A Cea-Olivares, R
Citation
M. Lopez-cardoso et al., Organometallic tin(IV) derivatives of the ambidentate O-cholesteryl-O-phenyl phosphorothioate ligand, POLYHEDRON, 19(13), 2000, pp. 1539-1543
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
19
Issue
13
Year of publication
2000
Pages
1539 - 1543
Database
ISI
SICI code
0277-5387(20000701)19:13<1539:OTDOTA>2.0.ZU;2-L
Abstract
Organotin(IV) compounds of the potentially ambidentate O-cholesteryl-O-phen yl phosphorothioate ligand formulated as Me3SnOSPR'R" (1), Ph3SnOSPR'R" (2) , O(CH2CH2,S)(2)Sn(n-Bu)OSPR'R'' (3), S(CH2CH2S)(2)Sn(n-Bu)OSPR'R" (4), (R' = O-Ph; R" = O-cholesteryl) were obtained and characterized by elemental a nalyses, IR, MS and multinuclear NMR (H-1, C-13, P-31 and Sn-119) spectrosc opy. The spectroscopic data are consistent with bonding of the phosphorothi oate ligand through both sulfur and oxygen atoms to the Sn(IV) center. (C) 2000 Elsevier Science Ltd. All rights reserved.