NEW METHOD OF ESTIMATING THE SOLID-SURFACE ENERGETIC HETEROGENEITY FROM TPD SPECTRA BASED ON THE STATISTICAL RATE THEORY OF INTERFACIAL TRANSPORT

Authors
RUDZINSKI W BOROWIECKI T DOMINKO A PANCZYK T
Citation
W. Rudzinski et al., NEW METHOD OF ESTIMATING THE SOLID-SURFACE ENERGETIC HETEROGENEITY FROM TPD SPECTRA BASED ON THE STATISTICAL RATE THEORY OF INTERFACIAL TRANSPORT, Langmuir, 13(13), 1997, pp. 3445-3453
Citations number
89
Categorie Soggetti
Chemistry Physical
Journal title
Langmuir → ACNP
ISSN journal
07437463
Volume
13
Issue
13
Year of publication
1997
Pages
3445 - 3453
Database
ISI
SICI code
0743-7463(1997)13:13<3445:NMOETS>2.0.ZU;2-I
Abstract
Recently a new theoretical method of a quantitative analysis of surfac e energetic heterogeneity from the experimental TPD spectra, based on the statistical rate theory of interfacial transport has been proposed by Rudzinski and co-workers. The purpose of the present publication i s to show the predictive features of that new method. Also prospects o f a further generalization of that method toward taking into account r eadsorption effects are discussed.