Trimethylsilyl derivatives of aliphatic nitro compounds in alpha,beta-C,C-cross-coupling

Authors
Dilman, AD Lyapkalo, IM Ioffe, SL Strelenko, YA Tartakovsky, VA
Citation
Ad. Dilman et al., Trimethylsilyl derivatives of aliphatic nitro compounds in alpha,beta-C,C-cross-coupling, RUSS CHEM B, 49(5), 2000, pp. 874-878
Citations number
13
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
5
Year of publication
2000
Pages
874 - 878
Database
ISI
SICI code
1066-5285(200005)49:5<874:TDOANC>2.0.ZU;2-X
Abstract
A new alpha,beta-C,C-cross-coupling reaction of derivatives of aliphatic ni tro compounds, silyl nitronates and N, N-bis(silyloxy)enamines, leading to beta-nitro oximes was found. The scope and limitations of this reaction wer e studied, and a mechanism was proposed.