3-alkenyl-5-ferrocenyl-2-pyrazolines in reactions with azodicarboxylic acid N-phenylimide

Citation
Ei. Klimova et al., 3-alkenyl-5-ferrocenyl-2-pyrazolines in reactions with azodicarboxylic acid N-phenylimide, RUSS CHEM B, 49(5), 2000, pp. 906-911
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
5
Year of publication
2000
Pages
906 - 911
Database
ISI
SICI code
1066-5285(200005)49:5<906:3IRWAA>2.0.ZU;2-C
Abstract
Azodicarboxylic acid N-phenylimide reacts with 1-acetyl-3-(2-ferrocenylethe nyl)-5-ferrocenyl-2-pyrazoline according to the [4+2]-cycloaddition mechani sm to form a Diels-Alder adduct. Under analogous conditions, 1-acetyl-5-fer rocenyl-3-(1-cyciohexenyl)-substituted 2-pyrazolines containing allylic hyd rogen atoms give monoene addition products.