Extraction of amino acids with di(2-ethylhexyl)phosphoric acid in the presence of dicyclohexyl-18-crown-6

Citation
Sv. Smirnova et al., Extraction of amino acids with di(2-ethylhexyl)phosphoric acid in the presence of dicyclohexyl-18-crown-6, RUSS CHEM B, 49(5), 2000, pp. 952-953
Citations number
12
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
5
Year of publication
2000
Pages
952 - 953
Database
ISI
SICI code
1066-5285(200005)49:5<952:EOAAWD>2.0.ZU;2-O
Abstract
Extraction of amino acids from aqueous solutions into chloroform with di(2- ethyl-hexyl)phosphoric acid was studied. The extraction efficiency decrease s in the sequence Tip > Phe > Leu > Arg > Lys > lie > Ata > Gly. The additi on of dicyclohexyl-18-crown-6 improves the efficiency. and kinetics of extr action of most amino acids. The extraction degree depends on the concentrat ion of the crown ether.