Energy of hydrogen bonding with the hydrogen atom in hydrides: Coordination H-2 bonds with boron hydride anions

Authors
Ionov, SP Kuznetsov, NT
Citation
Sp. Ionov et Nt. Kuznetsov, Energy of hydrogen bonding with the hydrogen atom in hydrides: Coordination H-2 bonds with boron hydride anions, RUSS J C CH, 26(8), 2000, pp. 527-530
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
26
Issue
8
Year of publication
2000
Pages
527 - 530
Database
ISI
SICI code
1070-3284(200008)26:8<527:EOHBWT>2.0.ZU;2-W
Abstract
The structural-thermodynamic model for the quantitative description of unco nventional hydrogen bonding with the hydrogen atom in hydrides (H-2 bond) i s presented. The energy of H-2 bonds is considered by using the interaction between water molecules and BH4,- B10H102-,B12H122-, and other anions as a n example and compared with the energy of a classical H bond. The H-2 bond is found to be 2-2.5 rimes weaker than the classical H bond.