Citation
Vb. Rybakov et al., Crystal structure of new U(IV) and U(V) complexes, RUSS J C CH, 26(8), 2000, pp. 594-598
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284
→ ACNP
Volume
26
Issue
8
Year of publication
2000
Pages
594 - 598
Database
ISI
SICI code
1070-3284(200008)26:8<594:CSONUA>2.0.ZU;2-K
Abstract
Synthesis, spectral investigation, and X-ray diffraction study of the (Cl3C
2N2S2)(+)(UCl6)(-) and [UCl2(OPCl3)(6)](2+)(UCl6)(2)(-) complexes were cond
ucted. Two types of uranium coordination polyhedra were found in the comple
xes studied: an octahedron (six chlorine atoms in the coordination sphere)
and a two-cap trigonal prism (six oxygen atoms of OPCl3 groups at the prism
vertices and two chlorine atoms centering the tetragonal faces).