Alkali and alkaline-earth metal boronitrides containing an N3- anion

Authors
Kulinich, SA Sevast'yanova, LG Zhukov, AN Burdina, KP
Citation
Sa. Kulinich et al., Alkali and alkaline-earth metal boronitrides containing an N3- anion, RUSS J G CH, 70(2), 2000, pp. 174-180
Citations number
30
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
2
Year of publication
2000
Pages
174 - 180
Database
ISI
SICI code
1070-3632(200002)70:2<174:AAAMBC>2.0.ZU;2-X
Abstract
The preparation conditions and properties of three new calcium, magnesium, and lithium boronitrides Ca6BN5, Mg6BN5, and Li3Mg3B2N5 were considered. Th e compounds were obtained by caking metal nitrides with boron nitride under atmospheric and high pressures. All these compounds are typical boronitrid e powders and, similarly to the known boronitride Mg3BN3, seem to contain a n N3- anion in their structure.