Shock sensitivity of a vinamidinium bis-perchlorate reagent and demonstration of a lower energy alternative

Authors
Ragan, JA McDermott, RE Jones, BP Ende, DJA Clifford, PJ McHardy, SJ Heck, SD Liras, S Segelstein, BE
Citation
Ja. Ragan et al., Shock sensitivity of a vinamidinium bis-perchlorate reagent and demonstration of a lower energy alternative, SYNLETT, (8), 2000, pp. 1172-1174
Citations number
4
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
8
Year of publication
2000
Pages
1172 - 1174
Database
ISI
SICI code
0936-5214(200008):8<1172:SSOAVB>2.0.ZU;2-G
Abstract
"Vinamidinium" bis-perchlorate salt 1 (2-dimethylaminomethylene-1,3-bis (di methylimmonio)-propane bis-perchlorate) was found to possess remarkably hig h thermal energy as well as significant shock sensitivity. A reported metho d for preparation of 2,5-disubstituted pyrimidines with 1 was of interest, and we found that the corresponding bis-tetrafluoroborate salt 2 was equall y effective in this transformation while possessing significantly lower the rmal energy.