A stereoselective synthetic route to (Z)-alpha-stannyl-alpha,beta-unsaturated aldehydes

Authors
Zhong, P Xiong, ZX Huang, X
Citation
P. Zhong et al., A stereoselective synthetic route to (Z)-alpha-stannyl-alpha,beta-unsaturated aldehydes, SYN COMMUN, 30(19), 2000, pp. 3535-3541
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
30
Issue
19
Year of publication
2000
Pages
3535 - 3541
Database
ISI
SICI code
0039-7911(2000)30:19<3535:ASSRT(>2.0.ZU;2-#
Abstract
Acetylenic stannanes 1 react with Cp2Zr(H)Cl (Cp = eta(5)-C5H5) and CO to g ive acylzirconocene choride: derivatives 2, which are trapped with dilute H Cl to afford (2)-alpha-stannyl-alpha,beta-unsaturated aldehydes 3.