The temperature dependences of the dielectric constant epsilon of sodium ni
obate single crystals NaNbO3 and sodium niobate-based (Na,Li)NbO3 and (Na,K
)NbO3 solid solutions with low content of the second component have been st
udied. A weak anomaly observed in epsilon(T) indicates a new phase transiti
on in the vicinity of 150 degrees C in NaNbO3 . The introduction of lithium
or potassium into NaNbO3 crystals increases the temperature of this transi
tion. The X-ray powder diffraction data suggest that the new transition tak
es place between two rhombohedral phases. (C) 2000 MAIK "Nauka/Interperiodi
ca".