Asymmetric hydrogen transfer reduction of ketones using chiral perfluorinated ligands

Citation
D. Maillard et al., Asymmetric hydrogen transfer reduction of ketones using chiral perfluorinated ligands, TETRAHEDR-A, 11(14), 2000, pp. 2881-2884
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
11
Issue
14
Year of publication
2000
Pages
2881 - 2884
Database
ISI
SICI code
0957-4166(20000728)11:14<2881:AHTROK>2.0.ZU;2-K
Abstract
Hydrogen transfer reduction of ketones occurs in a mixture of perfluoroalka ne/isopropanol using iridium complexes in association with chiral perfluoro salen ligands. An enantioselectivity of up to 60% was obtained. (C) 2000 El sevier Science Ltd. All rights reserved.